The Max message size limit is a special case worth mentioning, as it can be set as a Global limit as well as a Domain user limit and a User limit.
If the Global limit is checked and set in Mail Service - SMTP - Limits and Override Global limits is not checked then the limit set will be applied to all messages from all users in all domains on this server. Any message larger than the size set will be rejected.
If Override global limits is checked then the limits are checked in the following order until a non-zero value is found (if only zero values are found then the message is passed).
Example 1:
Any message with a size greater than 10MB will be rejected.
Example 2:
If UserA tries to send a message of size 40MB it will be accepted as his User limit (f) takes priority
If any other user in DomainA tries to send a message of size 40MB it will be rejected as it breaks the Domain limit (e) of 20MB
If UserB tries to send a message of size 40MB it will fail as it breaks the Mail Service Limit (a)